Pool Info: Metal Stains & Mineral Scale
Ah, the many hues of swimming pool water. A bit disconcerting when it happens, but at least there's a visual indication of a problem. Unless your friends are real practical jokers, we'll find the source of colored water to be either an animal, vegetable or mineral.
Organic problems such as algae and bacteria can discolor the water and deposit themselves on pool surfaces in a rainbow of greens, blacks, yellows, pinks. Algae deposits are distinguished from stains in that they are on the surface and not impregnated into the plaster. A more detailed discussion of their genesis and eventual destruction is covered in the algae page. Other organic materials such as leaves, worms, or other vegetable matter can also stain pool plaster. An organic stain can usually be removed by sprinkling granular chlorine over it. If it doesn't, its probably some other type of stain.
Inorganic materials like copper, iron, magnesium, calcium or aluminum can also cloud or discolor the pool water and stain or scale the pool surfaces, especially the plaster and tile grout. When a precipitated metallic salt such as calcium or magnesium remains in suspension, it can cause turbidity or cloudiness of the water. When heavy metal minerals are in suspension, they'll color the water. When these minerals quit floating around and decide to attach themselves or deposit on interior pool surfaces, the mineral salts such as carbonates of magnesium and calcium form a whitish crystallized deposit known as scale. If the precipitated minerals have color, as heavy metals often do, they will deposit themselves in the form of a stain.
In summary, precipitated (which means to come out of solution) carbonates of metallic salts will cloud the water and/or form crystal deposits on surfaces, while heavy metals will discolor the water and/or deposit themselves as stains.
|Calcium Plaster||Plaster, grout, mortar, cal-hypo chlorine shock||white crystals or precipitate|
|Cobalt||Fiberglass Shells||red, blue, gray, or black|
|Copper||Copper algaecides, ionizers, corrosion of copper and brass pipes, fittings and heaters||blue, green and blue/green, black, dark red, or teal|
|Iron||Well water, corrosion of iron pipe and fittings||dark, red, brown, black, gray or green|
|Manganese||Well water||pink, red, black or red|
Minerals like iron, calcium and copper exist naturally in trace amounts in your pool water. They may originate from the source water, that is, the water used to fill the pool. Well water is notoriously high in mineral content. Not much we can do about minerals entering in this manner. Other means of entry are more controllable.
Iron and copper pipes, fittings and equipment found in older pools are subject to corrosion by harsh chemical conditions, such as high chlorine and low pH. They also erode slowly with the everyday force of water rushing through. This corrosion and erosion releases heavy metal ions into the pool, which may be forced out of solution (precipitated), creating dramatic color schemes when free floating and stains when they deposit themselves.
Another source of metal ions occurs when two dissimilar metals are placed in close proximity to each other. For example, iron pipe connected to copper pipe, or a brass valve connected to aluminum equipment. These metals will attempt to exchange ions; water rushing in between them prevents the exchange, carrying off bits of their essence to the pool. This is the principle behind ionization systems.
A frequent source of copper discoloration and staining is the heat exchanger in the heater. Water rushing through the 8 or 10 tube, copper finned heat exchanger, at possibly higher than normal flow because of an oversized pump or faulty bypass valve, or containing corrosive water with high chlorine levels and/or low pH, will strip the copper right out. Corrosion and scaling conditions are dramatically increased by the high temperature found in heaters. As heat exchangers erode, the pool becomes stained and the exchanger tube walls become thin and begin to leak. ($$$)
Finally, staining can occur with the less than proper use of ionization systems and metal based algaecides. Copper is a known algaestat, while silver ions are a good bactericide. Copper and silver ionizers inject these metals into the water for contaminant control, however, if the water balance is out of control, or mineral levels are too high, staining can occur. The same is true for the algaecides, although some are chelated, which means they have agents contained in them to prevent minerals from coming out of solution.
Preventing Mineral Problems
Balanced pool water is such that it has neither a tendency towards corrosion or scaling. At the most basic level, pool water must be balanced to control stains and scale. pH or alkalinity that is allowed to drift and/or high calcium hardness levels can promote mineral precipitation.
The use of a sequestering agent is recommended for pools which have metal plumbing, fittings, heaters, ionizers or use metal algaecides or fill their pool with well water. These agents keep minerals tied up in solution like molecular glue. A chelator can also be used, which is electrostatically attracted to metals and minerals, enlarging to a particle size that can be removed by your pool filter. Chelators actually help remove metals from your pool water, while sequestering agents tied them up in solution (sequester them), to prevent their precipitation.
Pools using well water or water high in chloramines, sediment, minerals or metals can pre-filter pool fill water by using a garden hose attachment filter that will remove undesirable elements while the pool is being filled or topped off.
Correcting Mineral Problems
For pools that are discolored or cloudy due to precipitated minerals, the path back to blue may be accomplished by:
- Shock treatment with sodium or lithium hypochlorite, with constant filtration and clarifier use.
- Use of a flocculent to drop suspended particles to the floor for vacuuming.
- Use of a stain remover chemical, to reduce or remove pool stains.
- Partial drainage and dilution of the pool water, in cases where the pool water is saturated.
- Plaster pools can be drained and acid washed to remove metal stains or mineral deposits.
When TDS levels are too high, pool water can accommodate no more dissolved material and must throw off some of it in the form of precipitation. This is similar to the Jr. High science experiment where sugar or salt is continuously added to a glass of water until saturation is reached and it won't dissolve any more.